万物简史英文版_比尔·布莱森-第29章
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ttle lead into consumers鈥櫋ives。 however; nothing gave ita greater and more lasting intimacy than its addition to gasoline。
lead is a neurotoxin。 get too much of it and you can irreparably damage the brain andcentral nervous system。 among the many symptoms associated with overexposure areblindness; insomnia; kidney failure; hearing loss; cancer; palsies; and convulsions。 in its mostacute form it produces abrupt and terrifying hallucinations; disturbing to victims andonlookers alike; which generally then give way to a and death。 you really don鈥檛 want toget too much lead into your system。
on the other hand; lead was easy to extract and work; and almost embarrassingly profitableto produce industrially鈥攁nd tetraethyl lead did indubitably stop engines from knocking。 so in1923 three of america鈥檚 largest corporations; general motors; du pont; and standard oil ofnew jersey; formed a joint enterprise called the ethyl gasoline corporation (later shortenedto simply ethyl corporation) with a view to making as much tetraethyl lead as the world waswilling to buy; and that proved to be a very great deal。 they called their additive 鈥渆thyl鈥
because it sounded friendlier and less toxic than 鈥渓ead鈥潯nd introduced it for publicconsumption (in more ways than most people realized) on february 1; 1923。
almost at once production workers began to exhibit the staggered gait and confusedfaculties that mark the recently poisoned。 also almost at once; the ethyl corporationembarked on a policy of calm but unyielding denial that would serve it well for decades。 assharon bertsch mcgrayne notes in her absorbing history of industrial chemistry;prometheans in the lab; when employees at one plant developed irreversible delusions; aspokesman blandly informed reporters: 鈥渢hese men probably went insane because theyworked too hard。鈥潯ltogether at least fifteen workers died in the early days of production ofleaded gasoline; and untold numbers of others became ill; often violently so; the exactnumbers are unknown because the pany nearly always managed to hush up news ofembarrassing leakages; spills; and poisonings。 at times; however; suppressing the newsbecame impossible; most notably in 1924 when in a matter of days five production workersdied and thirty…five more were turned into permanent staggering wrecks at a single ill…ventilated facility。
as rumors circulated about the dangers of the new product; ethyl鈥檚 ebullient inventor;thomas midgley; decided to hold a demonstration for reporters to allay their concerns。 as hechatted away about the pany鈥檚 mitment to safety; he poured tetraethyl lead over hishands; then held a beaker of it to his nose for sixty seconds; claiming all the while that hecould repeat the procedure daily without harm。 in fact; midgley knew only too well the perilsof lead poisoning: he had himself been made seriously ill from overexposure a few monthsearlier and now; except when reassuring journalists; never went near the stuff if he could helpit。
buoyed by the success of leaded gasoline; midgley now turned to another technologicalproblem of the age。 refrigerators in the 1920s were often appallingly risky because they useddangerous gases that sometimes leaked。 one leak from a refrigerator at a hospital incleveland; ohio; in 1929 killed more than a hundred people。 midgley set out to create a gasthat was stable; nonflammable; noncorrosive; and safe to breathe。 with an instinct for theregrettable that was almost uncanny; he invented chlorofluorocarbons; or cfcs。
seldom has an industrial product been more swiftly or unfortunately embraced。 cfcs wentinto production in the early 1930s and found a thousand applications in everything from carair conditioners to deodorant sprays before it was noticed; half a century later; that they weredevouring the ozone in the stratosphere。 as you will be aware; this was not a good thing。
ozone is a form of oxygen in which each molecule bears three atoms of oxygen instead oftwo。 it is a bit of a chemical oddity in that at ground level it is a pollutant; while way up in thestratosphere it is beneficial; since it soaks up dangerous ultraviolet radiation。 beneficial ozoneis not terribly abundant; however。 if it were distributed evenly throughout the stratosphere; itwould form a layer just one eighth of an inch or so thick。 that is why it is so easily disturbed;and why such disturbances don鈥檛 take long to bee critical。
chlorofluorocarbons are also not very abundant鈥攖hey constitute only about one part perbillion of the atmosphere as a whole鈥攂ut they are extravagantly destructive。 one pound ofcfcs can capture and annihilate seventy thousand pounds of atmospheric ozone。 cfcs alsohang around for a long time鈥攁bout a century on average鈥攚reaking havoc all the while。
they are also great heat sponges。 a single cfc molecule is about ten thousand times moreefficient at exacerbating greenhouse effects than a molecule of carbon dioxide鈥攁nd carbondioxide is of course no slouch itself as a greenhouse gas。 in short; chlorofluorocarbons mayultimately prove to be just about the worst invention of the twentieth century。
midgley never knew this because he died long before anyone realized how destructivecfcs were。 his death was itself memorably unusual。 after being crippled with polio;midgley invented a contraption involving a series of motorized pulleys that automaticallyraised or turned him in bed。 in 1944; he became entangled in the cords as the machine wentinto action and was strangled。
if you were interested in finding out the ages of things; the university of chicago in the1940s was the place to be。 willard libby was in the process of inventing radiocarbon dating;allowing scientists to get an accurate reading of the age of bones and other organic remains;something they had never been able to do before。 up to this time; the oldest reliable dateswent back no further than the first dynasty in egypt from about 3000b。c。 no one couldconfidently say; for instance; when the last ice sheets had retreated or at what time in the pastthe cro…magnon people had decorated the caves of lascaux in france。
libby鈥檚 idea was so useful that he would be awarded a nobel prize for it in 1960。 it wasbased on the realization that all living things have within them an isotope of carbon calledcarbon…14; which begins to decay at a measurable rate the instant they die。 carbon…14 has ahalf…life鈥攖hat is; the time it takes for half of any sample to disappear1鈥攐f about 5;600 years;so by working out how much a given sample of carbon had decayed; libby could get a goodfix on the age of an object鈥攖hough only up to a point。 after eight half…lives; only 1/256 of theoriginal radioactive carbon remains; which is too little to make a reliable measurement; soradiocarbon dating works only for objects up to forty thousand or so years old。
curiously; just as the technique was being widespread; certain flaws within it becameapparent。 to begin with; it was discovered that one of the basic ponents of libby鈥檚formula; known as the decay constant; was off by about 3 percent。 by this time; however;thousands of measurements had been taken throughout the world。 rather than restate everyone; scientists decided to keep the inaccurate constant。 鈥渢hus;鈥潯im flannery notes; 鈥渆veryraw radiocarbon date you read today is given as too young by around 3 percent。鈥潯heproblems didn鈥檛 quite stop there。 it was also quickly discovered that carbon…14 samples can beeasily contaminated with carbon from other sources鈥攁 tiny scrap of vegetable matter; forinstance; that has been collected with the sample and not noticed。 for younger samples鈥攖hose under twenty thousand years or so鈥攕light contamination does not always matter somuch; but for older samples it can be a serious problem because so few remaining atoms arebeing counted。 in the first instance; to borrow from flannery; it is like miscounting by a dollarwhen counting to a thousand; in the second it is more like miscounting by a dollar when youhave only two dollars to count。
libby鈥檚 method was also based on the assumption that the amount of carbon…14 in theatmosphere; and the rate at which it has been absorbed by living things; has been consistentthroughout history。 in fact it hasn鈥檛 been。 we now know that the volume of atmosphericcarbon…14 varies depending on how well or not earth鈥檚 magnetism is deflecting cosmic rays;and that that can vary significantly over time。 this means that some carbon…14 dates are more1if you have ever wondered how the atoms determine which 50 percent will die and which 50 percent willsurvive for the next session; the answer is that the half…life is really just a statistical convenience…a kind ofactuarial table for elemental things。 imagine you had a sample of material with a half…life of 30 seconds。 it isntthat every atom in the sample will exist for exactly 30 seconds or 60 seconds or 90 seconds or some other tidilyordained period。 each atom will in fact survive for an entirely random length of time that has nothing to do withmultiples of 30; it might last until two seconds from now or it might oscillate away for years or decades orcenturies to e。 no one can say。 but what we can say is that for the sample as a whole the rate ofdisappearance will be such that half the atoms will disappear every 30 seconds。 its an average rate; in otherwords; and you can apply it to any large sampling。 someone once worked out; for instance; that dimes have ahalf…life of about 30 years。
dubious than others。 this is particularly so with dates just around the time that people firstcame to the americas; which is one of the reasons the matter is so perennially in dispute。
finally; and perhaps a little unexpectedly; readings can be thrown out by seeminglyunrelated external factors鈥攕uch as the diets of those whose bones are being tested。 onerecent case involved the long…running debate over whether syphilis originated in the newworld or the old。 archeologists in hull; in the north of england; found that monks in amonastery graveyard had suffered from syphilis; but the initial conclusion that the monks haddone so before columbus鈥檚 voyage was cast into doubt by the realization that they had eaten alot of fish; which could make their bones appear to be older than in fact they were。 the monksmay well have had syphilis; but how it got to them; and when; remain tantalizinglyunresolved。
because of the accumulated shortings of carbon…14; scientists devised other methods ofdating ancient materials; among them thermoluminesence; which measures electrons trappedin clays; and electron spin resonance; which involves bombarding a sample withelectromagnetic waves and measuring the vibrations of the electrons。 but even the best ofthese could not date anything older than about 200;000 years; and they couldn鈥檛 date inorganicmaterials like rocks at all; which is of course what you need if you wish to determine the ageof your planet。
the problems of dating rocks were such that at one point almost everyone in the world hadgiven up on them。 had it not been for a determined english professor named arthur holmes;the quest might well have fallen into abeyance altogether。
holmes was heroic as much for the obstacles he overcame as for the results he achieved。
by the 19